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Posted on May 29, 1992July 12, 2018 by Davies Group

30. Highly stereoselective [3 + 2] annulations by cyclopropanation of vinyl ethers with rhodium(II)-stabilized vinylcarbenoids followed by a formally forbidden 1,3-sigmatropic rearrangement

Authors: Huw M. L. Davies , Baihua Hu

J. Org. Chem.,

1992, 57 (11), 3186–3190

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CategoriesPublications Tagsannulation, Cyclopropanation, Rhodium(II), vinyl carbenoid, [3+2]

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Research Topics

  • 7-membered ring
  • aldol
  • alkyne
  • amines
  • annulation
  • carbenoid
  • Catalyst Design
  • chiral auxiliaries
  • chiral ligand
  • cocaine
  • Cope-Rearrangement
  • cycloaddition
  • cyclopentene
  • Cyclopropanation
  • cyclopropenation
  • C–H Functionalization
  • C–H Functionalization/Cope-Rearrangement
  • diazo
  • Donor/Acceptor
  • dopamine transporters
  • DOSP
  • furan
  • heterocycles
  • Immobilized
  • indole
  • inter-molecular
  • intra-molecular
  • Natural Product
  • PTAD
  • pyridine
  • pyrrole
  • Rhodium(II)
  • ring expansion
  • serotonin transporters
  • silver
  • tandem
  • triazole
  • tropane
  • vinyl carbenoid
  • vinylogous reactivity
  • ylide
  • Ylide Formation
  • [3+2]
  • [3+4]
  • [4+3]

CCHF Symposium [2019] – Dr. Huw Davies

https://youtu.be/TCPWeqMa-nI

NOS Lecture [2019] – Dr. Huw Davies

https://youtu.be/3RJhsMioczA
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