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30. Highly stereoselective [3 + 2] annulations by cyclopropanation of vinyl ethers with rhodium(II)-stabilized vinylcarbenoids followed by a formally forbidden 1,3-sigmatropic rearrangement

May 29, 1992July 12, 2018 Davies Group

Authors: Huw M. L. Davies , Baihua Hu

J. Org. Chem.,

1992, 57 (11), 3186–3190

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Publications annulation, Cyclopropanation, Rhodium(II), vinyl carbenoid, [3+2]. permalink.

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29. Regioselective [3 + 2] annulations with rhodium(ii)-stabilized vinylcarbenoids
31. Ring expansion of tert-butyl 1-vinylcyclopropane-1-carboxylates to .alpha.-ethylidenebutyrolactones
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Research Topics

7-membered ring aldol alkyne amines annulation carbenoid Catalyst Design chiral auxiliaries chiral ligand cocaine Cope-Rearrangement cycloaddition cyclopentene Cyclopropanation cyclopropenation C–H Functionalization C–H Functionalization/Cope-Rearrangement diazo Donor/Acceptor dopamine transporters DOSP furan heterocycles Immobilized indole inter-molecular intra-molecular Natural Product PTAD pyridine pyrrole Rhodium(II) ring expansion serotonin transporters silver tandem triazole tropane vinyl carbenoid vinylogous reactivity ylide Ylide Formation [3+2] [3+4] [4+3]
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