50. Control of carbenoid reactivity through neighboring group participation

Authors: Huw M.L. Davies, Julius J. Matasi, Craig Thornley

Tetrahedron Lett., 

199536, 7205–7208

Product distribution in the rhodium(II) carboxylate catalyzed decomposition of vinyldiazomethanes in the presence of N-(BOC)pyrroles can be controlled through stabilization of the vinylcarbenoid intermediates by neighboring group participation

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