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Posted on June 27, 1989July 12, 2018 by Davies Group

20. Stereoselective cyclopropanations with vinylcarbenoids

Authors: Huw M.L Davies, T.Jeffrey Clark, Linda A Church

Tetrahedron Lett., 

1989, 30, 5057-5060

1-s2.0-S004040390193446X-gr1

Rhodium(II) acetate catalyzed decomposition of vinyldiazomethanes in the presence of alkenes results in cyclopropanation with a high degree of stereoselectivity.

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CategoriesPublications TagsCyclopropanation, vinyl carbenoid

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