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Breaking the Rules of Chemistry

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Tag: vinylogous reactivity

Posted on November 14, 2013July 12, 2018

249. Silver-Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates

Authors: Changming Qin and Huw M. L. Davies

Org. Lett.,

2013, 15 (24), pp 6152–6154

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Continue reading “249. Silver-Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates”

Posted on August 26, 2013July 12, 2018

248. Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers

Authors: John F. Briones and Huw M. L. Davies

J. Am. Chem. Soc.,

2013, 135 (36), 13314–13317

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Continue reading “248. Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers”

Posted on October 25, 2012July 12, 2018

237. Rhodium-Catalyzed Enantioselective Vinylogous Addition of Enol Ethers to Vinyldiazoacetates

Authors: Austin G. Smith and Huw M. L. Davies

J. Am. Chem. Soc.,

2012, 134 (44), 18241–18244

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Continue reading “237. Rhodium-Catalyzed Enantioselective Vinylogous Addition of Enol Ethers to Vinyldiazoacetates”

Posted on April 24, 2012July 12, 2018

229. Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton

Authors: Daniel Morton,   Allison R. Dick,   Debashis Ghosh and   Huw M. L. Davies

Chem. Commun.,

2012, 48, 5838-5840

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Continue reading “229. Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton”

Posted on November 22, 2011July 12, 2018

226. Vinylogous reactivity of silver(I) vinylcarbenoids

Authors: Jørn H. Hansen and Huw M. L. Davies

Chem. Sci.,

2011, 2, 457-461

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Continue reading “226. Vinylogous reactivity of silver(I) vinylcarbenoids”

Posted on March 25, 2008July 12, 2018

191. Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids

Authors: Yulia Sevryugina, Beth Weaver, Jørn Hansen, Janelle Thompson, Huw M. L. Davies and Marina A. Petrukhin

Organometallics,

2008, 27 (8), 1750–1757

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Continue reading “191. Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids”

Posted on August 29, 1994July 12, 2018

43. Carbenoid versus Vinylogous Reactivity in Rhodium(II)-Stabilized Vinylcarbenoids

Authors: Huw M. L. Davies , Baihua Hu , Elie Saikali , Paul R. Bruzinski

J. Org. Chem.,

1994, 59 (16), 4535–4541

Continue reading “43. Carbenoid versus Vinylogous Reactivity in Rhodium(II)-Stabilized Vinylcarbenoids”

Research Topics

  • 7-membered ring
  • aldol
  • alkyne
  • amines
  • annulation
  • carbenoid
  • Catalyst Design
  • chiral auxiliaries
  • chiral ligand
  • cocaine
  • Cope-Rearrangement
  • cycloaddition
  • cyclopentene
  • Cyclopropanation
  • cyclopropenation
  • C–H Functionalization
  • C–H Functionalization/Cope-Rearrangement
  • diazo
  • Donor/Acceptor
  • dopamine transporters
  • DOSP
  • furan
  • heterocycles
  • Immobilized
  • indole
  • inter-molecular
  • intra-molecular
  • Natural Product
  • PTAD
  • pyridine
  • pyrrole
  • Rhodium(II)
  • ring expansion
  • serotonin transporters
  • silver
  • tandem
  • triazole
  • tropane
  • vinyl carbenoid
  • vinylogous reactivity
  • ylide
  • Ylide Formation
  • [3+2]
  • [3+4]
  • [4+3]

CCHF Symposium [2019] – Dr. Huw Davies

https://youtu.be/TCPWeqMa-nI

NOS Lecture [2019] – Dr. Huw Davies

https://youtu.be/3RJhsMioczA
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