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Breaking the Rules of Chemistry

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Tag: ylide

Posted on December 8, 2010July 12, 2018

210. Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols

Authors: Zhanjie Li and Huw M. L. Davies

J. Am. Chem. Soc.,

2010, 132 (1), 396–401

027

Continue reading “210. Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols”

Posted on December 4, 2003July 12, 2018

137. C–H Insertion Reactions, Cycloadditions and Ylide Formation of Diazo Compounds

Authors: Huw M. L. Davies

Comprehensive Asymmetric Catalysis

2003, 83

Continue reading “137. C–H Insertion Reactions, Cycloadditions and Ylide Formation of Diazo Compounds”

Posted on December 29, 1996July 12, 2018

58. Sulfur Ylides from Metal Carbenoids

Authors: Huw M. L. Davies

Nitrogen, Oxygen and Sulfur Ylide Chemistry

1996, Oxford University Press,

Ed: Stephen Clark

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Posted on January 27, 1987July 12, 2018

12. Synthesis and pyrolysis of cyclic sulfonium ylides

Authors: Huw M.L Davies, L.Van T Crisco

Tetrahedron Lett. 

1987, 28, 371-374

1-s2.0-S0040403900957319-gr1

Continue reading “12. Synthesis and pyrolysis of cyclic sulfonium ylides”

Research Topics

  • 7-membered ring
  • aldol
  • alkyne
  • amines
  • annulation
  • carbenoid
  • Catalyst Design
  • chiral auxiliaries
  • chiral ligand
  • cocaine
  • Cope-Rearrangement
  • cycloaddition
  • cyclopentene
  • Cyclopropanation
  • cyclopropenation
  • C–H Functionalization
  • C–H Functionalization/Cope-Rearrangement
  • diazo
  • Donor/Acceptor
  • dopamine transporters
  • DOSP
  • furan
  • heterocycles
  • Immobilized
  • indole
  • inter-molecular
  • intra-molecular
  • Natural Product
  • PTAD
  • pyridine
  • pyrrole
  • Rhodium(II)
  • ring expansion
  • serotonin transporters
  • silver
  • tandem
  • triazole
  • tropane
  • vinyl carbenoid
  • vinylogous reactivity
  • ylide
  • Ylide Formation
  • [3+2]
  • [3+4]
  • [4+3]

CCHF Symposium [2019] – Dr. Huw Davies

https://youtu.be/TCPWeqMa-nI

NOS Lecture [2019] – Dr. Huw Davies

https://youtu.be/3RJhsMioczA
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