{"id":681,"date":"2011-05-10T13:35:27","date_gmt":"2011-05-10T18:35:27","guid":{"rendered":"http:\/\/scholarblogs.emory.edu\/davieslab\/?p=681"},"modified":"2018-07-12T14:01:41","modified_gmt":"2018-07-12T19:01:41","slug":"217-sequential-transformations-to-access-polycyclic-chemotypes-asymmetric-crotylation-and-metal-carbenoid-reactions","status":"publish","type":"post","link":"https:\/\/scholarblogs.emory.edu\/davieslab\/2011\/05\/10\/217-sequential-transformations-to-access-polycyclic-chemotypes-asymmetric-crotylation-and-metal-carbenoid-reactions\/","title":{"rendered":"217. Sequential Transformations to Access Polycyclic Chemotypes: Asymmetric Crotylation and Metal Carbenoid Reactions"},"content":{"rendered":"<p>Authors:\u00a0Jie Wu, Dr. Jorge Becerril, Yajing Lian, Prof.\u2005Dr. Huw M. L. Davies, Prof.\u2005Dr. John A. Porco Jr., Prof.\u2005Dr. James S. Panek<\/p>\n<p><em>Angew., Chem. Int. Ed.<\/em><\/p>\n<p><strong>2011<\/strong>,\u00a0<em>50,<\/em>\u00a026, 5938-5942<\/p>\n<p style=\"text-align: center\"><a href=\"http:\/\/scholarblogs.emory.edu\/davieslab\/files\/2013\/12\/033.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-medium wp-image-682\" alt=\"033\" src=\"http:\/\/scholarblogs.emory.edu\/davieslab\/files\/2013\/12\/033-300x98.gif\" width=\"300\" height=\"98\" \/><\/a><\/p>\n<p style=\"text-align: left\"><!--more--><\/p>\n<p style=\"text-align: left\">All in order: Bicyclic and tricyclic chemotypes were accessed through the title transformations. By subsequent pairing of installed functional groups using Heck cyclization or [2+2]\u2005photocycloaddition, the synthesis of tetracycles, pentacycles, and condensed polycycles has been achieved with high stereochemical and skeletal variation.<\/p>\n<p style=\"text-align: left\"><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201101366\/abstract\" target=\"_blank\">Read More<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Authors:\u00a0Jie Wu, Dr. Jorge Becerril, Yajing Lian, Prof.\u2005Dr. Huw M. L. Davies, Prof.\u2005Dr. John A. Porco Jr., Prof.\u2005Dr. James S. Panek Angew., Chem. Int. Ed. 2011,\u00a050,\u00a026, 5938-5942<\/p>\n","protected":false},"author":5441,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[8],"tags":[16,38,14,30],"class_list":["post-681","post","type-post","status-publish","format-standard","hentry","category-publications","tag-carbenoid","tag-donoracceptor","tag-rhodiumii","tag-vinyl-carbenoid"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>217. 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