39. Enantioselective synthesis of vinylcyclopropanes by rhodium(II) catalyzed decomposition of vinyldiazomethanes in the presence of alkenes

Authors: Huw M.L. Davies, Debra K. Hutcheson

Tetrahedron Lett., 

199334, 7243-7246

1-s2.0-S0040403900792987-gr1

Rhodium(II) N-(arenesulfonyl)prolinate catalyzed decomposition of vinyldiazomethanes in the presence of alkenes resulted in highly diastereoselective and enantioselective cyclopropanations.

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