Authors: Huw M.L. Davies, Tore Hansen, James Rutberg, Paul R. Bruzinski
Tetrahedron Lett.,
1997, 38, 10, 1741-1744
Allylsilanes or benzylsilanes of high enantiomeric purity (77–95% ee) are formed from the rhodium(II) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate (1) catalyzed decomposition of vinyldiazomethanes or phenyldiazomethanes in the presence of dimethylphenylsilane (3).