Publications

Emory Publications

20. Wallen, C. W.; Palatinus, L.; Bacsa, J.; Scarborough, C. C. “Hydrogen Peroxide Coordination to Cobalt(II) Facilitated by Second-Sphere Hydrogen Bonding” Angewandte Chemie, International Edition 2016, 55, In Press. [link]
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19. Karahalis, G. J.; Thangavel, A.; Chica, B.; Bacsa, J.; Dyer, R. B.; Scarborough, C. C. “Synthesis and Catalytic Reactivity of a Dicopper(II) μ–η2:η2-Peroxo Species Supported by 1,4,7-Tri-tert-butyl-1,4,7-triazacyclononane” Inorganic Chemistry 2016, 51, 1102-1107. [link]
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18. Wallen, C. M.; Wieliczko, M.; Bacsa, J.; Scarborough, C. C. “Heterotrimetallic Sandwich Complexes Supported by Sulfonamido Ligands” Inorganic Chemistry Frontiers 2016, 3, 142-149 (invited contribution to the 2016 Emerging Investigator issue). [link]
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17. Wallen, C. M.; Bacsa, J.; Scarborough, C. C. “Hydrogen Peroxide Complex of Zinc” Journal of the American Chemical Society 2015, 137, 14606-14609. [link]
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16. Thangavel, A.; Wieliczko, M.; Scarborough, C. C.; Dittrich, B.; Bacsa, J. “An Investigation of the Electron Density of a Jahn–Teller-distorted CrII Cation: the Crystal Structure and Charge Density of a Hexakis(acetonitrile-κN)-Chromium(II) Bis(tetraphenylborate) Acetonitrile Disolvate” Acta Crystallographica 2015, C71, 936-943. [link]

15. Thangavel, A.; Wieliczko, M.; Bacsa, J.; Scarborough, C. C. “1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents” Inorganic Chemistry 2013, 52, 13282-13287. [link].
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Prior to Emory
14. Rodriguez, M. M.; Stubbert, B. D.; Scarborough, C. C.; Brennessel, W. W.; Bill, E.; Holland, P. L. “Isolation and Characterization of Stable Iron(I)-Sulfide Complexes” Angewandte Chemie, International Edition 2012, 51, 8247-8250. [link]

13. Scarborough, C. C.; Sproules, S.; Doonan, C. J.; Hagen, K. S.; Weyhermüller, T.; Wieghardt, K. “Scrutinizing Low-Spin Cr(II) Complexes” Inorganic Chemistry 2012, 51, 6969-6982. [link]

12. England, J.; Scarborough, C. C.; Weyhermüller, T.; Sproules, S.; Wieghardt, K. “Electronic Structures of the Electron Transfer Series [M(bpy)3]n, [M(tpy)3]n, and [Fe(tbpy)3]n (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1–): A Mössbauer Spectroscopic and DFT Study” European Journal of Inorganic Chemistry 2012, 4605-4621. [link]

11. Scarborough, C. C.; Lancaster, K. M.; DeBeer, S.; Weyhermüller, T.; Sproules, S.; Wieghardt, K. “Experimental Fingerprints for the Redox-Active Terpyridine in [Cr(tpy)2](PF6)n (n = 3–0), and the Remarkable Electronic Structure of [Cr(tpy)2]1–” Inorganic Chemistry 2012, 51, 3718-3732.[link]

10. Chiang, K. P.; Scarborough, C. C.; Horitani, M.; Lees, N. S.; Ding, K.; Dugan, T. R.; Brennessel, W. W.; Bill, E.; Hoffman, B. M.; Holland, P. L. “Characterization of the Fe–H Bond in a Three-Coordinate Terminal Hydride Complex of Iron(I)” Angewandte Chemie, International Edition 2012, 51, 3718-3722. [link]

9.  Scarborough, C. C.; Sproules, S.; Weyhermüller, T.; DeBeer, S.; Wieghardt, K. “Electronic and Molecular Structures of the Members of the Electron Transfer Series [Cr(tbpy)3]n (n = 3+, 2+, 1+, 0): An X-ray Absorption Spectroscopic and Density Functional Theoretical Study” Inorganic Chemistry 2011, 50, 12446-12462. [link]

8. Scarborough, C. C.; Wieghardt, K. “The Electronic Structure of 2,2’-Bipyridine Organotransition Metal Complexes. Establishing the Ligand Oxidation Level by Density Functional Theoretical Calculations” Inorganic Chemistry 2011, 50, 9773-9793. [link]

7.Scarborough, C. C.; Bergant, A.; Sazama, G. T.; Guzei, I. A.; Spencer, L. C.; Stahl, S. S. “Synthesis of PdII Complexes Bearing an Enantiomerically Resolved Seven-Membered N-Heterocyclic Carbene Ligand and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions” Tetrahedron 2009, 65, 5084-5092. [link]

6.Scarborough, C. C., McDonald, R. I.; Hartmann, C.; Sazama, G. T.; Bergant, A.; Stahl, S. S. “Steric Modulation of Chiral Biaryl Diamines via Pd-Catalyzed Directed C–H Arylation” Journal of Organic Chemistry 2009, 74, 2613-2615. [link]

5.Scarborough, C. C., Guzei, I. A.; Stahl, S. S. “Synthesis and Isolation of a Stable, Axially-Chiral Seven-Membered N-Heterocyclic Carbene” Dalton Transactions 2009, 2284-2286. [link]

4.Kotov, V.; Scarborough, C. C.; Stahl, S. S. “Palladium-Catalyzed Aerobic Oxidative Amination of Alkenes: Development of Intra- and Intermolecular Aza-Wacker Reactions” Inorganic Chemistry 2007, 46, 1910-1923. [link]

3.Scarborough, C. C.; Stahl, S. S. “Synthesis of Pyrrolidines via Palladium-Catalyzed Aerobic Oxidative Carboamination of Butyl Vinyl Ether and Styrenes with Allyl Tosylamides” Organic Letters 2006, 8, 3251-3254. [link]

2.Scarborough, C. C.; Popp, B. V.; Guzei, I. A.; Stahl, S. S. “Development of 7-Membered N-heterocyclic Carbene Ligands for Transition Metals” Journal of Organometallic Chemistry 2005,690, 6143-6155. [link]

1.Scarborough, C. C.; Grady, M. J. W.; Guzei, I. A.; Gandhi, B. A.; Bunel, E. E.; Stahl, S. S. “PdIIComplexes Possessing a Seven-Membered N-Heterocyclic Carbene Ligand” Angewandte Chemie, International Edition 2005, 44, 5269-5272. [link]

Patents
1. “Seven-Membered Heterocyclic Carbenes and their Metal Complexes,” Stahl, S. S.; Scarborough, C. C. EP20060733854, January 23, 2008.