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23. Stereoselective synthesis of seven-membered carbocycles by a tandem cyclopropanation/Cope rearrangement between rhodium(II)-stabilized vinylcarbenoids and dienes

June 27, 1991July 12, 2018 Davies Group

Authors: Huw M. L. Davies , T. Jeffrey Clark , H. David Smith

J. Org. Chem.,

1991, 56 (12), 3817–3824

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Publications 7-membered ring, Cope-Rearrangement, Cyclopropanation, Rhodium(II), tandem, vinyl carbenoid. permalink.

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22. Stereoselective convergent synthesis of hydroazulenes via an intermolecular cyclopropanation/Cope rearrangement
24. Synthesis of (.+-.)-ferruginine and (.+-.)-anhydroecgonine methyl-ester by a tandem cyclopropanation/Cope rearrangement
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Research Topics

7-membered ring aldol alkyne amines annulation carbenoid Catalyst Design chiral auxiliaries chiral ligand cocaine Cope-Rearrangement cycloaddition cyclopentene Cyclopropanation cyclopropenation C–H Functionalization C–H Functionalization/Cope-Rearrangement diazo Donor/Acceptor dopamine transporters DOSP furan heterocycles Immobilized indole inter-molecular intra-molecular Natural Product PTAD pyridine pyrrole Rhodium(II) ring expansion serotonin transporters silver tandem triazole tropane vinyl carbenoid vinylogous reactivity ylide Ylide Formation [3+2] [3+4] [4+3]
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