92. Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene

Authors: Huw M.L Davies, Douglas G Stafford, Tore Hansen, Melvyn Rowen Churchill, Kim M Keil

Tetrahedron Lett.,

20004113, 2035-2038

Rhodium prolinate catalyzed reactions of diazocarbonyls with cycloheptatriene are very dependent on the carbenoid structure and can result in either cyclopropanation, C–H insertion or a combined C–H insertion Cope rearrangement.

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