133. Direct gas-phase interaction of aryldiazoacetates and dirhodium catalysts

Authors: Marina A. Petrukhina,   Kristian W. Andreini, Abbas M. Walji and Huw M. L. Davies

Dalton Trans.,

2003, 4221-4223


Interaction of two dirhodium catalysts [Rh2(O2CR)4] (R = CMe3 and CF3) with methyl-p-methoxyphenyldiazoacetate in the gas phase has resulted in the partial or complete loss of dinitrogen from diazo substrate and afforded two new hybrid products that are of interest for the further development of catalytic processes.

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