155. Universal Strategy for the Immobilization of Chiral Dirhodium Catalysts

Authors: Huw M. L. Davies and Abbas M. Walji

Org. Lett.,

2005, 7 (14), 2941–2944


Chiral rhodium(II) catalysts used in asymmetric carbenoid chemistry can be efficiently heterogenized using a novel immobilization strategy. The immobilized catalysts display similar reactivity and stereoselectivity to their homogeneous counterparts and can be effectively recycled with limited loss in stereoselectivity.

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