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186. Total Synthesis of Natural Products using the Combined C–H Functionalization/Cope Rearrangement as the Key Step

December 6, 2007July 12, 2018 Davies Group

Authors: Xing Dai and Huw M. L. Davies

In Strategies and Tactics in Organic Synthesis

2007, 7, 383-407

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Publications C–H Functionalization/Cope-Rearrangement, DOSP, Natural Product, Rhodium(II). permalink.

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185. ONE-FLASK SYNTHESIS OF METHYL ARYLVINYLDIAZOACETATES AND THEIR APPLICATION IN ENANTIOSELECTIVE C-H FUNCTIONALIZATION: SYNTHESIS OF (E)-METHYL 2-DIAZO-4-PHENYLBUT-3-ENOATE AND (S,E)-METHYL 2-((R)-4-METHYL-1,2-DIHYDRONAPHTHALEN-2-YL)-4-PHENYLBUT-3-ENOATE
187. Asymmetric [4 + 3] Cycloadditions between Benzofuranyldiazoacetates and Dienes:  Formal Synthesis of (+)-Frondosin B
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Research Topics

7-membered ring aldol alkyne amines annulation carbenoid Catalyst Design chiral auxiliaries chiral ligand cocaine Cope-Rearrangement cycloaddition cyclopentene Cyclopropanation cyclopropenation C–H Functionalization C–H Functionalization/Cope-Rearrangement diazo Donor/Acceptor dopamine transporters DOSP furan heterocycles Immobilized indole inter-molecular intra-molecular Natural Product PTAD pyridine pyrrole Rhodium(II) ring expansion serotonin transporters silver tandem triazole tropane vinyl carbenoid vinylogous reactivity ylide Ylide Formation [3+2] [3+4] [4+3]
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