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Posted on May 12, 2016July 12, 2018 by Davies Group

271: Site-selective and stereoselective functionalization of unactivated C–H bonds

Authors: Kuangbiao Liao, Solymar Negretti, Djamaladdin G. Musaev, John Bacsa & Huw M. L. Davies

Nature

2016, 533, 230–234

nature17651-f1

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NATURE HIGHLIGHT: Organic chemistry: Precision pruning of molecules

CEN HIGHLIGHT: Custom dirhodium catalysts zero in on select alkane bonds

ANGEWANDTE HIGHLIGHT Functionalization of Unactivated C(sp3)−H Bonds Using Metal-Carbene Insertion Reactions

SYNFACTS HIGHLIGHT Site- and Stereoselective Functionalization of Nonactivated Alkanes

Press Release: Chemists find ‘huge shortcut’ for organic synthesis using C-H bonds

CategoriesPublications Tagsalkane, C2 selectivity, Catalyst Design, catalyst library synthesis, catalyst toolbox, chiral ligand, cross coupling, C–H Functionalization, diastereoselective, Donor/Acceptor, enantioselective, regioselective, Rhodium(II), Selective C-H insertion, unactivated C–H bonds

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