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Breaking the Rules of Chemistry

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Category: Publications

Posted on February 29, 1992July 12, 2018

29. Regioselective [3 + 2] annulations with rhodium(ii)-stabilized vinylcarbenoids

Authors: Huw M.L. Davies, Baibua Hu

Tetrahedron Lett., 

1992, 33, 455-456

Continue reading “29. Regioselective [3 + 2] annulations with rhodium(ii)-stabilized vinylcarbenoids”

Posted on January 27, 1992July 12, 2018

28. SYNTHESIS OF FURANS VIA RHODIUM(II) ACETATE-CATALYZED REACTION OF ACETYLENES WITH α-DIAZOCARBONYLS: ETHYL 2-METHYL-5-PHENYL-3-FURANCARBOXYLATE

Authors: Huw M. L. Davies, William R. Cantrell, Jr, Karen R. Romines, and Jonathan S. Baum

Org. Syn., 

1992, 70, 93

CV9P0422

Continue reading “28. SYNTHESIS OF FURANS VIA RHODIUM(II) ACETATE-CATALYZED REACTION OF ACETYLENES WITH α-DIAZOCARBONYLS: ETHYL 2-METHYL-5-PHENYL-3-FURANCARBOXYLATE”

Posted on December 27, 1991July 12, 2018

27. Addition of Ketocarbenes to Alkenes, Alkynes and Aromatic Systems

Author: Huw M.L. Davies

Comprehensive Organic Synthesis

1991, 1031-1067

Continue reading “27. Addition of Ketocarbenes to Alkenes, Alkynes and Aromatic Systems”

Posted on November 27, 1991July 12, 2018

26. α-hydroxy esters as inexpensive chiral auxiliaries in rhodium(II)-catalyzed cyclopropanations with vinyldiazomethanes

Authors: Huw M.L. Davies, William R. Cantrell Jr.

Tetrahedron Lett.,

1991, 32, 6509-6512

1-s2.0-004040399180206L-gr1

Continue reading “26. α-hydroxy esters as inexpensive chiral auxiliaries in rhodium(II)-catalyzed cyclopropanations with vinyldiazomethanes”

Posted on October 27, 1991July 12, 2018

25. Versatile synthesis of tropones by reaction of rhodium(II)-stabilized vinylcarbenoids with 1-methoxy-1-[(trimethylsilyl)oxy]buta-1,3-diene

Authors: Huw M. L. Davies , T. Jeffrey Clark , Garland F. Kimmer

J. Org. Chem.,

1991, 56 (22), 6440–6447

Continue reading “25. Versatile synthesis of tropones by reaction of rhodium(II)-stabilized vinylcarbenoids with 1-methoxy-1-[(trimethylsilyl)oxy]buta-1,3-diene”

Posted on September 27, 1991July 12, 2018

24. Synthesis of (.+-.)-ferruginine and (.+-.)-anhydroecgonine methyl-ester by a tandem cyclopropanation/Cope rearrangement

Authors: Huw M. L. Davies , Elie Saikali , Wendy B. Young

J. Org. Chem.,

1991, 56 (19), 5696–5700

Continue reading “24. Synthesis of (.+-.)-ferruginine and (.+-.)-anhydroecgonine methyl-ester by a tandem cyclopropanation/Cope rearrangement”

Posted on June 27, 1991July 12, 2018

23. Stereoselective synthesis of seven-membered carbocycles by a tandem cyclopropanation/Cope rearrangement between rhodium(II)-stabilized vinylcarbenoids and dienes

Authors: Huw M. L. Davies , T. Jeffrey Clark , H. David Smith

J. Org. Chem.,

1991, 56 (12), 3817–3824

Continue reading “23. Stereoselective synthesis of seven-membered carbocycles by a tandem cyclopropanation/Cope rearrangement between rhodium(II)-stabilized vinylcarbenoids and dienes”

Posted on January 27, 1991July 12, 2018

22. Stereoselective convergent synthesis of hydroazulenes via an intermolecular cyclopropanation/Cope rearrangement

Authors: William R. Cantrell Jr., Huw M. L. Davies

J. Org. Chem.,

1991, 56 (2), 723–727

Continue reading “22. Stereoselective convergent synthesis of hydroazulenes via an intermolecular cyclopropanation/Cope rearrangement”

Posted on November 27, 1990July 12, 2018

21. Anomalous reactivity of mono substituted rhodium stabilized vinylcarbenoids

Authors: Huw M.L. Davies, Elie Saikali, T. Jeffrey Clark, Edwin H. Chee

Tetrahedron Lett., 

1990, 31, 6299-6302

1-s2.0-S0040403900970473-gr1

Continue reading “21. Anomalous reactivity of mono substituted rhodium stabilized vinylcarbenoids”

Posted on June 27, 1989July 12, 2018

20. Stereoselective cyclopropanations with vinylcarbenoids

Authors: Huw M.L Davies, T.Jeffrey Clark, Linda A Church

Tetrahedron Lett., 

1989, 30, 5057-5060

1-s2.0-S004040390193446X-gr1

Continue reading “20. Stereoselective cyclopropanations with vinylcarbenoids”

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NOS Lecture [2019] – Dr. Huw Davies

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