95. Regiochemistry of molybdenum-catalyzed O–H insertions of vinylcarbenoids

Authors: Huw M.L. Davies, Yasuno Yokota

Tetrahedron Lett.,

20004125, 4851-4854

Molybdenum-catalyzed decomposition of vinyldiazoacetates generates vinylcarbenoids that preferentially react with alcohols at the vinylogous position of the vinylcarbenoid rather than at the carbenoid site.

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