Materials composed of immobilized water oxidation catalysts on metal oxide supports have recently become a significant target in the field of solar fuels, for their use in the production of devices. These materials utilize electrostatic and atomic-layer deposition (ALD) protection techniques to bind POM WOCs and the light-absorbing supports (TiO2, BiVO4, and CdS quantum dots) for photoelectrochemical water oxidation systems.
![](https://scholarblogs.emory.edu/hill/files/2018/11/wateroxidationOld.png)
Chem. Mater., 2015, 27, 5886
Water Oxidation Catalysts
The Hill lab has pioneered the development of efficient, stable, homogeneous molecular catalysts for visible light-driven water oxidation using polyoxometalates (POMs). Recent studies have characterized the catalytic activity and stability of POMs containing ruthenium, cobalt, and nickel centers.
![]() Inorg. Chem. 2022, 61, 16, 6252–6262 |
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